Jump to content

Period 3

From Archania

In the periodic table, a period is a horizontal row of elements. Period 3 is the third row, encompassing the eight elements with atomic numbers 11 through 18 – from sodium to argon. All Period 3 elements have three electron shells in their atoms, and as we move from left to right across this period, the outermost shell gains electrons and the element properties gradually shift. Period 3 is particularly fascinating because it showcases a diverse range of element types: it begins with reactive metals, passes through a metalloid (silicon), then into nonmetals, and ends with a noble gas. This means the chemical behavior changes dramatically across the row – from the explosive metal sodium to the inert gas argon – illustrating many fundamental trends of the periodic table in one small set of elements. Despite their differences, the Period 3 elements are all important in our daily lives, found in common substances like table salt, glass, and fertilizers, as well as in the technology and materials that shape our modern world.

Sodium (Na) – Reactive Metal of Salt and Light

Main article: Periodic table/Alkali metals/Sodium

Orbital grid of Sodium ([Ne] 3s1)

Sodium (atomic number 11) is a soft, silvery-white metal and the first element of Period 3. It belongs to the alkali metals and is highly reactive – so much so that pure sodium metal is never found in nature, as it immediately combines with other elements. In fact, sodium famously reacts explosively with water, producing hydrogen gas and a caustic solution of sodium hydroxide; this vigorous reaction is a classic chemistry demonstration. Because of its reactivity, elemental sodium must be stored under oil and handled with care. Compounds of sodium, however, are abundant and indispensable. Sodium chloride (common table salt) is the most familiar example – it makes up a large portion of the dissolved minerals in the oceans and was historically so important that Roman soldiers were partly paid in salt (the origin of the word “salary”). In the human body, sodium ions are essential electrolytes: they help transmit nerve impulses and regulate fluids, which is why a modest salt intake is necessary for life. Industry also makes extensive use of sodium and its compounds. For example, sodium vapor lamps, the classic streetlights, emit a characteristic yellow glow and are filled with sodium gas. Pure sodium metal has specialized uses too – it’s used as a coolant in certain nuclear reactors and as a reagent in making other metals and chemicals. In short, this “wild” element that flashes and bursts in water also lies quietly on our dinner tables in the form of salt, playing a dual role as a dangerous metal and a life-sustaining nutrient.

Magnesium (Mg) – Light Metal That Burns Bright

Main article: Periodic table/Alkaline earth metals/Magnesium

Orbital grid of Magnesium ([Ne] 3s2)

Right next to sodium in Period 3 is magnesium (atomic number 12), a shiny gray metal that is lightweight but strong. Magnesium is an alkaline earth metal and is one-third lighter than aluminum by density. If you’ve ever seen old-fashioned flash photography or sparklers, you’ve glimpsed magnesium’s famous trait: it ignites easily in air and burns with a brilliant white flame. This intense white light made magnesium powder a key ingredient in early photographic flashes, flares, and fireworks. Beyond pyrotechnics, magnesium’s low weight and good strength make it ideal for structural alloys. It’s often alloyed with aluminum to create materials used in airplane parts, car engines, and portable electronics – wherever a strong but lightweight metal is needed. Everyday items like some laptop casings, camera bodies, or even car seats can contain magnesium-alloy components. On the chemical side, compounds of magnesium have many uses too. Magnesium oxide (sometimes called magnesia) is used to make heat-resistant bricks for furnaces. Magnesium hydroxide, known as “milk of magnesia,” is a common antacid and laxative, while magnesium sulfate (Epsom salts) is used in bath salts and gardening. Biologically, magnesium is essential to all living things – it sits at the heart of the chlorophyll molecule, enabling plants to photosynthesize (without magnesium, plants couldn’t capture sunlight to make food). Our bodies also rely on magnesium in hundreds of enzymes; we get magnesium from green vegetables, nuts, and whole grains in our diet. Thus, magnesium is a metal that not only shines brightly in a flame but also quietly supports life and modern technology through its versatile applications.

Aluminium (Al) – Abundant Lightweight Metal

Main article: Periodic table/Boron group/Aluminium

Orbital grid of Aluminium ([Ne] 3s2 3p1)

Aluminium (atomic number 13) – spelled aluminium in British English – is a silvery-white, malleable metal and is the most abundant metal in Earth’s crust. In fact, about 8% of the crust is aluminum, making it the third most abundant element overall (after oxygen and silicon). This abundance, however, belies the fact that pure aluminum metal was once more valuable than gold: it was difficult to extract until the late 19th century, when the Hall–Héroult process made aluminum cheaply available. Aluminum’s popularity comes from its combination of properties. It is very lightweight (low density), non-magnetic, and resistant to corrosion – it naturally forms a thin oxide coating that prevents rusting. It’s also an excellent conductor of heat and electricity. Thanks to these traits, aluminum is ubiquitous in modern life. We use it in transportation (for aircraft frames, car parts, bicycle frames) and construction (window frames, building facades) because it’s strong yet light. In the kitchen, aluminum foil and beverage cans are common objects – aluminum’s malleability lets it be rolled into thin foil or shaped into cans easily. You’ll also find aluminum in appliances, power lines (as an electrical conductor), and packaging. For example, aluminum coatings are used on telescope mirrors and snack bag linings for reflectivity. Another advantage is that aluminum is highly recyclable – it can be remelted and reused indefinitely with little loss of quality, saving energy compared to extracting new metal. Interestingly, aluminum has no known biological role in the human body – we don’t need it nutritionally, and in soluble forms it can even be toxic to plants and possibly linked (unconfirmed) to health issues in humans. Fortunately, the metal in solid form (like in a soda can) doesn’t harm us, and we encounter it safely every day. From the frame of your smartphone to the foil covering your leftovers, aluminum’s presence in daily life is a testament to its useful, adaptable nature – truly a “miracle metal” of the modern age.

Silicon (Si) – Elemental Backbone of Tech and Earth

Main article: Periodic table/Carbon group/Silicon

Orbital grid of Silicon ([Ne] 3s2 3p2)

Silicon (atomic number 14) is a metalloid, sitting at the border between metals and nonmetals, and it plays a dual identity in our world. On one hand, silicon is famous as the shiny, gray semiconductor that underpins the entire electronics industry – the “silicon” in Silicon Valley. Ultra-pure silicon crystals, carefully “doped” with tiny amounts of other elements, form the chips and transistors in our computers and smartphones. Silicon’s ability to act as a semiconductor (conducting electricity under some conditions but not others) makes it ideal for microelectronics and solar panels. On the other hand, silicon is also a geological giant: it is the second most abundant element in Earth’s crust (about 27% by mass) after oxygen. In nature it doesn’t appear as free silicon but is always tied up with oxygen in silicates and silica. Common sand, for example, is silicon dioxide (SiO₂, also called silica), and it’s the primary ingredient of glass. The rocks beneath our feet – granite, quartz, clay, and many minerals – are largely silicates of silicon. Because of this, silicon is everywhere around us: in concrete (made from sand and gravel), in porcelain and ceramics, in glass windows and bottles, and more. Even many types of soils and clays are rich in silicon compounds, which help give structure to the earth. Humans have long taken advantage of silicon’s compounds, from making glass since ancient times to today’s use of silicone sealants (flexible silicon-based polymers) that waterproof bathrooms and windows. Biologically, silicon is not believed to be essential for human metabolism, but it is important for some plants and microscopic life – for instance, tiny algae called diatoms build their intricate shells out of silica. In summary, silicon is a true all-rounder: it forms the literal bedrock of the planet and the sand on our beaches, and simultaneously it’s the material that enables the information age, connecting this very moment of you reading about it on an electronic screen.

Phosphorus (P) – Life’s Spark and the Matchstick

Main article: Periodic table/Pnictogens/Phosphorus

Orbital grid of Phosphorus ([Ne] 3s2 3p3)

Phosphorus (atomic number 15) is a nonmetal that comes in several different forms, the most common being white phosphorus and red phosphorus. In its pure form, phosphorus was the first element isolated by modern chemistry – Hennig Brand discovered it in 1669 by famously boiling down buckets of urine, eventually obtaining a waxy white substance that glowed in the dark. (The name “phosphorus” comes from Greek for “light-bearer” due to white phosphorus’s faint greenish glow.) White phosphorus is highly reactive: it will ignite spontaneously in air if warm, burning with a bright flame, and it’s notoriously toxic. Early uses of white phosphorus took advantage of its flammability – it was used in old-fashioned matchsticks, fireworks, and even incendiary weapons (tracer bullets, smoke bombs, and horrific fire-bombs in warfare). However, because white phosphorus is so dangerous (match factory workers in the 1800s developed “phossy jaw,” a severe bone disease, from exposure), it was replaced by safer red phosphorus in matches. Red phosphorus does not ignite in air and is used on the striking surface of safety matchboxes instead of in the match head, eliminating the worst health hazards. Beyond its fiery persona, phosphorus is absolutely critical for life. In nature, phosphorus is never found as the pure element but always as phosphate (combining with oxygen). Phosphate compounds are one of the three primary nutrients in fertilizers (the “P” in N-P-K ratios) because phosphorus is essential for plant growth. In the human body and all living cells, phosphorus is a structural and functional superstar: it’s part of DNA and RNA (the genetic material), part of ATP (the energy molecule that powers our cells), and a major component of our bones and teeth in the form of calcium phosphate. Every time you drink a soda with phosphoric acid or use a dish detergent with phosphates, you’re using phosphorus compounds. Modern agriculture depends on mined phosphate rock turned into phosphoric acid – tens of millions of tons per year are produced for fertilizers. So phosphorus has this dual identity: it’s the fiery element of matches and flame, but also the element of biology and growth. As some say, phosphorus is the “DNA in our genes and the flame in our fireworks” – an element of vitality in more ways than one.

Sulfur (S) – The Yellow Brimstone

Main article: Periodic table/Chalcogens/Sulfur

Orbital grid of Sulfur ([Ne] 3s2 3p4)

Sulfur (atomic number 16) is a bright yellow nonmetal that has been known since antiquity – it’s the biblical “brimstone” associated with lightning and volcanoes. In its pure form sulfur is found around volcanic vents and hot springs as an elemental mineral with a distinctive yellow crystalline appearance. Chemically, sulfur is best recognized by its smell (or rather, the smell of many of its compounds). While sulfur itself is odorless, when it burns it produces sulfur dioxide, the acrid scent of a struck match, and many sulfur compounds (like hydrogen sulfide) smell like rotten eggs or skunk spray. Despite these stinky associations, sulfur is an immensely important element industrially and biologically. The majority of sulfur harvested (often as a byproduct of oil and gas refining) is used to produce sulfuric acid, H₂SO₄. Sulfuric acid is sometimes called the “king of chemicals” because it’s used in so many processes – most notably in making phosphate fertilizers. Indeed, sulfuric acid helps turn rock phosphate into soluble fertilizer, linking sulfur to food production worldwide. Elemental sulfur also has direct uses: it’s a key ingredient in vulcanizing rubber, the process that Charles Goodyear discovered to make natural rubber tough and durable for tires. Sulfur is used in fungicides and insecticides (to protect crops) and was historically in black gunpowder (combined with charcoal and saltpeter). Another everyday use of sulfur compounds is in the form of sulfites and sulfates – sulfite preservatives keep dried fruits and wines from spoiling, and sulfate compounds are used in detergents and paper whitening. On the biological side, sulfur is one of the essential elements of life. It’s a component of two essential amino acids (cysteine and methionine), which means all proteins contain sulfur, and it’s present in vitamins like biotin and thiamine. Your body has about 0.2% sulfur by weight, mostly in your proteins. Plants absorb sulfur from soil as sulfate, and it cycles through the environment (though excess sulfur released by burning fossil fuels can cause acid rain). In summary, sulfur is an element of contradictions: a yellow rock from volcanoes that smells of rotten eggs when it reacts, yet it is critical in manufacturing, agriculture, and the very proteins of our bodies. It’s no wonder sulfur has been both revered and reviled through history – part of “fire and brimstone” mythology, and part of the fundamental chemistry of life.

Chlorine (Cl) – Green Gas with a Dual Nature

Main article: Periodic table/Halogens/Chlorine

Orbital grid of Chlorine ([Ne] 3s2 3p5)

Chlorine (atomic number 17) is a halogen element and is most familiar as a greenish-yellow gas with a sharp, choking odor. In its elemental form, Cl₂ gas, chlorine is very reactive and toxic – it was infamously used as a poison gas in World War I. However, this dangerous aspect is only one side of chlorine’s story. In compounds, especially as chloride (Cl⁻), chlorine is far more benign and in fact essential for life. Sodium chloride, common table salt, is the most well-known chloride; our bodies depend on it to regulate fluids and transmit nerve signals (we literally need a bit of salt in our diet every day). Chlorine’s most significant use is as a disinfectant. It has strong germ-killing and bleaching properties. Small amounts of chlorine-based compounds (like sodium hypochlorite or calcium hypochlorite) are added to drinking water and swimming pools to destroy harmful bacteria, making water safe to use. Household chlorine bleach is used to whiten laundry and sanitize surfaces – its potency comes from chlorine’s ability to oxidize and break down pigments and microbes. Beyond sanitation, chlorine is a workhorse of the chemical industry. About 19% of all chlorine produced is used in bleaches and disinfectants, but an even larger portion (well over half) goes into manufacturing organic chemicals. For example, chlorine is essential in producing PVC (polyvinyl chloride) plastic, a common material for pipes, vinyl flooring, and cable insulation. Many solvents, refrigerants (like old CFCs), and pharmaceuticals contain chlorine atoms in their molecules. If you’ve taken certain medicines, worn synthetic dyes, or used plastic goods, chlorine was likely involved in their production. In the environment, chlorine is usually found as chloride in seawater (chloride is the number one dissolved ion in the ocean, by weight). Naturally, elemental chlorine is rare on Earth because it reacts to form salts readily – for instance, vast deposits of halite (rock salt) are sodium chloride. In summary, chlorine is an element of strong contrasts: as a gas it’s hazardous, but in controlled compounds it keeps our water clean and enables countless products. It’s the element that bleaches white our cotton, disinfects our pools, and helps form sturdy plastics – truly both a protector and, in its elemental state, a potent toxin. Handling chlorine requires care, but our modern public health and industry would be hard-pressed to do without it.

Argon (Ar) – The Inert Noble Gas

Main article: Periodic table/Noble gases/Argon

Orbital grid of Argon ([Ne] 3s2 3p6)

Argon (atomic number 18) completes Period 3 as a noble gas, and true to that family name it is chemically inert. Colorless, odorless, tasteless, and non-toxic, argon gas doesn’t normally react with anything – it just floats around, quietly minding its own business. In fact, the name “argon” comes from the Greek word for “inactive” or “lazy,” reflecting this lack of reactivity. Argon makes up about 0.93% of Earth’s atmosphere by volume, which may sound small but actually ranks it as the third most abundant atmospheric gas (after nitrogen and oxygen). Every breath you take has a bit of argon in it. This argon is mostly radiogenic, formed over eons by the decay of potassium in the Earth’s crust and then released to the air. Because argon is so unreactive, it has some specialized but crucial applications. One major use is as an inert shielding gas in high-temperature industrial processes like arc welding. When metals are welded or melted, exposure to air could cause oxidation or contamination; a blanket of argon gas protects the hot metal by displacing oxygen. Argon is also the gas often found in ordinary incandescent light bulbs (the classic filament bulbs) and in fluorescent tubes. If those bulbs were filled with air, the hot tungsten filament would burn out quickly; argon’s presence prevents the filament from oxidizing and evaporating, greatly extending the bulb’s life. Similarly, double-pane insulated windows are sometimes filled with argon gas to improve thermal insulation. In more advanced tech, argon finds use in certain types of lasers (argon-ion lasers emit a distinctive blue-green light) and in scientific apparatus that require an oxygen-free environment. Discoverers Lord Rayleigh and William Ramsay were astonished by argon’s inertness when they identified it in 1894, as it formed no compounds easily. To this day, argon has no known compounds stable at room temperature (only under extreme conditions can it be coaxed into combining with other elements). For living organisms, argon has no biological role – we simply inhale and exhale it unchanged. But thanks to argon’s “lazy” nature, we have a go-to gas for protecting materials from unwanted reactions. It’s the silent preserver in welding workshops and light bulbs, an invisible buffer that quietly does its job by doing almost nothing at all – the noble gas indeed.

Comparing the Period 3 Elements

To summarize the elements of Period 3, the table below highlights each element with its symbol, atomic number, and a key use or notable property:

Element Symbol Atomic Number Key Use/Property
Sodium Na 11 Component of table salt; essential for nerve function.
Magnesium Mg 12 Lightweight metal for alloys; burns bright in flares and fireworks.
Aluminum Al 13 Lightweight, corrosion-resistant metal used in aircraft, cars, and cans.
Silicon Si 14 Semiconductor used in computer chips; also main ingredient in glass (sand is SiO₂).
Phosphorus P 15 Essential for life (DNA, bones, ATP); widely used in fertilizers.
Sulfur S 16 Yellow nonmetal used to produce sulfuric acid for fertilizers; used in vulcanizing rubber.
Chlorine Cl 17 Reactive green gas used to disinfect water (in bleach) and to produce PVC plastic.
Argon Ar 18 Inert noble gas (~1% of air) used in light bulbs and as a welding shield gas.

Each of these Period 3 elements contributes in unique ways to science, technology, and everyday life. From forming the salt that seasons and preserves our food to enabling the electronics we rely on, Period 3’s elements collectively demonstrate the richness of the periodic table – a journey in one row from reactive metal to inert gas, reflecting the broader order and diversity of all the elements.